382434

(S)-(−)-1,1′-Binaphthyl-2,2′-diamine

99%

Manufacturer: Sigma Aldrich

CAS Number: 18531-95-8

Synonym(S): (S)-(−)-1,1′-Bi(2-naphthylamine), (S)-(−)-1,1′-Binaphthalene-2,2′-diamine, (S)-(−)-2,2′-Diamino-1,1′-binaphthalene, (S)-(−)-DABN

Select a Size

Pack Size SKU Availability Price
1 G 382434-1-G In Stock ₹ 16,324.10

382434 - 1 G

₹ 16,324.10

In Stock

Quantity

1

Base Price: ₹ 16,324.10

GST (18%): ₹ 2,938.338

Total Price: ₹ 19,262.438

Quality Level

200

Assay

99%

optical activity

[α]20/D −157°, c = 1 in pyridine

optical purity

ee: 99% (HPLC)

mp

242-244 °C (lit.)

SMILES string

Nc1ccc2ccccc2c1-c3c(N)ccc4ccccc34

InChI

1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2

InChI key

DDAPSNKEOHDLKB-UHFFFAOYSA-N

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Description

  • Application: (S)-(-)-1,1′-Binaphthyl-2,2′-diamine may be used in the synthesis of (S)-(+)-N,N′-dimethyl-N,N′-bis{3-[bis-(1-methyl-2-benzimidazolyl methyl)]-amino]-propyl}-1,1′-binaphthyl-2,2′-diamine, an octadentate ligand that can form dinuclear and trinuclear copper(II) complexes.[1] It may also be used in the synthesis of (Sa)-N-[2´-amino-(1,1´-binaphthyl)-2-yl]-4-methylbenzenesulfonamide.[2]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves