699918

(R)-N-[(1R,2R)-2-(3-(3,5-Bis(trifluoromethyl)phenyl)ureido)cyclohexyl]-tert-butyl-sulfinamide

96%

Manufacturer: Sigma Aldrich

CAS Number: 934762-68-2

Synonym(S): [S(R)]-N-[(1R,2R)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]carbonyl]amino]cyclohexyl]-2-methyl-2-propanesulfinamide

Select a Size

Pack Size SKU Availability Price
100 MG 699918-100-MG In Stock ₹ 6,051.18
500 MG 699918-500-MG In Stock ₹ 26,185.68

699918 - 100 MG

₹ 6,051.18

In Stock

Quantity

1

Base Price: ₹ 6,051.18

GST (18%): ₹ 1,089.212

Total Price: ₹ 7,140.392

Quality Level

100

Assay

96%

form

solid

mp

173-181 °C

SMILES string

CC(C)(C)S(=O)N[C@@H]1CCCC[C@H]1NC(=O)Nc2cc(cc(c2)C(F)(F)F)C(F)(F)F

InChI

1S/C19H25F6N3O2S/c1-17(2,3)31(30)28-15-7-5-4-6-14(15)27-16(29)26-13-9-11(18(20,21)22)8-12(10-13)19(23,24)25/h8-10,14-15,28H,4-7H2,1-3H3,(H2,26,27,29)/t14-,15-,31-/m1/s1

InChI key

WMIJNZVQFOPOBW-ZHANGXNJSA-N

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Description

  • Application: (R)-N-[(1R,2R)-2-(3-(3,5-Bis(trifluoromethyl)phenyl)ureido)cyclohexyl]-tert-butyl-sulfinamide is a sulfinamide-urea based chiral catalyst that can be used to synthesize: Enantioselective homoallylic amines by asymmetric allylation of acylhydrazones with allylindium reagents.[1] Tetrahydroquinolines via an asymmetric Povarov reaction.[2] 2-aryl-substituted cycloalkanones by enantioselective protonation of corresponding trimethylsilyl enol ethers.[3]

SAFETY INFORMATION

Hazard Statements

H413

Hazard Classifications

Aquatic Chronic 4

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves