725455

Rhodium(II) triphenylacetate dimer

as complex with dichloromethane

Manufacturer: Sigma Aldrich

CAS Number: 142214-04-8

Synonym(S): Rh2(TPA)4, Rh2(triphenylacetate)4, Rhodiumtriphenylacetate, Tetrakis(triphenylacetato)dirhodium(II)

Select a Size

Pack Size SKU Availability Price
100 MG 725455-100-MG In Stock ₹ 10,700.40

725455 - 100 MG

₹ 10,700.40

In Stock

Quantity

1

Base Price: ₹ 10,700.40

GST (18%): ₹ 1,926.072

Total Price: ₹ 12,626.472

Quality Level

100

form

solid

reaction suitability

core: rhodiumreagent type: catalystreaction type: C-H Activation

mp

260-263 °C

SMILES string

ClCCl.O=C(O[Rh](OC(=O)C(c1ccccc1)(c2ccccc2)c3ccccc3)[Rh](OC(=O)C(c4ccccc4)(c5ccccc5)c6ccccc6)OC(=O)C(c7ccccc7)(c8ccccc8)c9ccccc9)C(c%10ccccc%10)(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C20H16O2.CH2Cl2.2Rh/c4*21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1-3;;/h4*1-15H,(H,21,22);1H2;;/q;;;;;2*+2/p-4

InChI key

SRAMLXDHXNCYQM-UHFFFAOYSA-J

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Description

  • Application: Catalyst for:Amination of allene carbamatesAllene aziridination to stereoselectively prepare cyclic cabamatesC-H bond nitrene insertionEnantioselective cyclopropanationPreparation of cyclic oxonium ylides

SAFETY INFORMATION

Pictograms

GHS08

Signal Word

Warning

Hazard Statements

H351

Precautionary Statements

P201 - P202 - P280 - P308 + P313 - P405 - P501

Hazard Classifications

Carc. 2

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable