Description

• General description: Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared.[1] It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes.[2] Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.[3]
• Application: Silver trifluoromethanesulfonate (AgOTf) may be employed as a reagent during glucosylation of several alcohols.[1] AgOTf in combination with p-nitrobenzenesulfenyl chloride may be employed as an activator for the glycosylation.[4]It may be used for the synthesis of the following:cystine-containing peptides[5]3-aminoalkylated indoles[6]benzo[b]oxepines and 2H-chromenes[7]diversely substituted iminoimidazoazines[8]
• Other Notes: Reagent for the substitution of halides by triflate.; Reagent for the glycosylation of glycosyl halides[9][10][11]; Reagent used for the deprotection of protected thiols[12]