494992
Ethyl 2,3-butadienoate
95%
Manufacturer: Sigma Aldrich
CAS Number: 14369-81-4
Synonym(S): (Ethoxycarbonyl)allene, Ethyl allenecarboxylate, Ethyl butadienoate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 494992-1-G | In Stock | ₹ 10,456.95 |
| 5 G | 494992-5-G | In Stock | ₹ 32,604.90 |
494992 - 1 G
In Stock
Quantity
1
Base Price: ₹ 10,456.95
GST (18%): ₹ 1,882.251
Total Price: ₹ 12,339.201
Quality Level
100
Assay
95%
refractive index
n20/D 1.46 (lit.)
bp
80 °C/60 mmHg (lit.)
density
0.966 g/mL at 25 °C (lit.)
SMILES string
[H]C([H])=C=C([H])C(=O)OCC
InChI
1S/C6H8O2/c1-3-5-6(7)8-4-2/h5H,1,4H2,2H3
InChI key
GLSUOACRAMLJIW-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
eMolecules AstaTech / ETHYL 23-BUTADIENOATE / 1g / 448280466 / T71774 / 95.000 / 14369-81-4 / MFCD01863567 / 112.128 / C6H8O2 | -- | ₹ 12,445.76 | ||
Sigma Aldrich Fine Chemicals Biosciences Ethyl 2,3-butadienoate 95% | Purity: 95% | Mol Wt: 112.13 | 14369-81-4 | MFCD01863567 | 5G | -- | ₹ 42,411.17 | ||
Ethyl 2,3-butadienoate | -- | ₹ 4,717.00 - ₹ 58,473.00 | ||
14369-81-4 | 2,3-Butadienoic acid, ethyl ester | -- | ₹ 3,382.00 - ₹ 64,436.00 |
Related Products
Description
- General description: Ethyl 2,3-butadienoate is an α-allenic ester. The reaction of ethyl 2,3-butadienoate with N-tosylated imines in the presence of DABCO (1,4-diazabicyclo[2.2.2]octane) or DMAP (4-dimethylaminopyridine) forms azetidine derivatives or novel dihydropyridine derivatives respectively.[1] The performance of bifunctional N-acyl aminophosphines to catalyze the asymmetric [3+2] cycloaddition of phenylidenemalononitrile with ethyl 2,3-butadienoate has been evaluated.[2]
- Application: Ethyl 2,3-butadienoate may be used in the synthesis of dihydropyrans by reacting with acyclic enones.[3] It may also be used to synthesize spiranic heterocycles by reacting with heterocyclic bis-arylidene ketones via phosphine-catalyzed [3+2] annulations.[4]
SAFETY INFORMATION
Pictograms
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 3
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves