496820

4-Vinyl-1,3-dioxolan-2-one

99%

Manufacturer: Sigma Aldrich

CAS Number: 4427-96-7

Synonym(S): VEC, Vinyl ethylene carbonate

Select a Size

Pack Size SKU Availability Price
25 G 496820-25-G In Stock ₹ 3,518.13
100 G 496820-100-G In Stock ₹ 13,368.88
1 KG 496820-1-KG In Stock ₹ 19,582.43
5 KG 496820-5-KG In Stock ₹ 68,673.80

496820 - 25 G

₹ 3,518.13

In Stock

Quantity

1

Base Price: ₹ 3,518.13

GST (18%): ₹ 633.263

Total Price: ₹ 4,151.393

Quality Level

100

Assay

99%

refractive index

n20/D 1.45 (lit.)

bp

237 °C/733 mmHg (lit.)

density

1.188 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C=CC1COC(=O)O1

InChI

1S/C5H6O3/c1-2-4-3-7-5(6)8-4/h2,4H,1,3H2

InChI key

BJWMSGRKJIOCNR-UHFFFAOYSA-N

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Description

  • General description: 4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic carbonate, that can be synthesized from acrolein by reacting with sulfur ylide and CO2.[1] The ruthenium-catalyzed transfer hydrogenation (TH) of VEC in the presence of 2-propanol forms 1,2-butanediol.[2] Indolines and indoles undergo selective C-H allylation with VEC in the presence of rhodium(III) catalyst.[3]
  • Application: 4-Vinyl-1,3-dioxolan-2-one may be used in the preparation of 2-arylbenzo[d]thiazole scaffolds.[4]It may be used in the synthesis of the following multi-functional cyclic carbonates:[5]4,4′-((hexane-1,6-diylbis(sulfanediyl))bis-(ethane-2,1-diyl))bis(1,3-dioxolan-2-one) (Bis-CC)2-ethyl-2-(((3-((2-(2-oxo-1,3-dioxolan-4-yl)-ethyl)thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tris-CC)2,2-bis(((3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)-thio)propanoyl)oxy) methyl)propane-1,3-diyl bis(3-((2-(2-oxo-1,3-dioxolan-4-yl)ethyl)thio)propanoate) (Tetra-CC)

SAFETY INFORMATION

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H301

Precautionary Statements

P264 - P270 - P301 + P310 - P405 - P501

Hazard Classifications

Acute Tox. 3 Oral

WGK

WGK 1

Flash Point(F)

206.4 °F

Flash Point(C)

96.9 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves