157910

Methyl bromoacetate

97%

Manufacturer: Sigma Aldrich

CAS Number: 96-32-2

Synonym(S): 2-Bromoacetic acid methyl ester, Bromoacetic acid methyl ester, Carbomethoxymethyl bromide, Methyl α-bromoacetate, Methyl 2-bromoacetate, Methyl 2-bromoethanoate

Select a Size

Pack Size SKU Availability Price
25 G 157910-25-G In Stock ₹ 2,370.68
100 G 157910-100-G In Stock ₹ 3,886.18

157910 - 25 G

₹ 2,370.68

In Stock

Quantity

1

Base Price: ₹ 2,370.68

GST (18%): ₹ 426.722

Total Price: ₹ 2,797.402

Quality Level

200

Assay

97%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

51-52 °C/15 mmHg (lit.)

density

1.616 g/mL at 25 °C (lit.)

SMILES string

COC(=O)CBr

InChI

1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3

InChI key

YDCHPLOFQATIDS-UHFFFAOYSA-N

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Description

  • General description: Methyl bromoacetate is an α-bromo ester. Reactions of the methyl bromoacetate with conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) yields alkylated carbene complexes.[1]
  • Application: Methyl bromoacetate was used in the synthesis of novel coumarins.[2] It was also employed in the synthesis of cis-cyclopropanes.[3]

SAFETY INFORMATION

Pictograms

GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301,H314,H317

Precautionary Statements

P261 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

147.2 °F

Flash Point(C)

64 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves