376264

Trimethyl(propargyl)silane

contains 500 ppm BHT as stabilizer

Manufacturer: Sigma Aldrich

CAS Number: 13361-64-3

Synonym(S): 2-Propynyl-trimethylsilane, 3-(Trimethylsilyl)propyne

Select a Size

Pack Size SKU Availability Price
1 G 376264-1-G In Stock ₹ 13,580.00

376264 - 1 G

₹ 13,580.00

In Stock

Quantity

1

Base Price: ₹ 13,580.00

GST (18%): ₹ 2,444.40

Total Price: ₹ 16,024.40

form

liquid

Quality Level

200

contains

500 ppm BHT as stabilizer≤20% trimethylallenylsilane (in equilibrium)

refractive index

n20/D 1.413 (lit.)

bp

91-93 °C (lit.)

density

0.753 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

C[Si](C)(C)CC#C

InChI

1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3

InChI key

ULYLMHUHFUQKOE-UHFFFAOYSA-N

Other Options

Description

  • General description: Trimethyl(propargyl)silane (2-Propynyl-trimethylsilane) is a clear colorless liquid and contains 500ppm of butylated hydroxytoluene (BHT) as stabilizer. It undergoes GaCl3-catalyzed dehydrogenation reaction with aldimines to afford 4-methylquinoline.[1]
  • Application: Trimethyl(propargyl)silane is suitable for use in the synthesis of diverse end-functionalized (ω-carboxyl, ω-hydroxy, ω-methyl-vinyl, ω-trimethylsilane, and ω-glycidyl-ether) via ′′click′′ reaction.[2] It may be used in the synthesis of γ-allenyl-GABA (γ-aminobutyric acid), via Lewis acid mediated reaction with ω-ethoxy lactams.[3]
  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.

SAFETY INFORMATION

Pictograms

GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Precautionary Statements

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

23.0 °F

Flash Point(C)

-5 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves