378755

Dichlorotriphenylphosphorane

95%

Manufacturer: Sigma Aldrich

CAS Number: 2526-64-9

Synonym(S): Triphenylphosphine dichloride

Select a Size

Pack Size SKU Availability Price
25 G 378755-25-G In Stock ₹ 6,256.85
100 G 378755-100-G In Stock ₹ 17,211.75

378755 - 25 G

₹ 6,256.85

In Stock

Quantity

1

Base Price: ₹ 6,256.85

GST (18%): ₹ 1,126.233

Total Price: ₹ 7,383.083

Quality Level

200

Assay

95%

form

solid

mp

85 °C (dec.) (lit.)

SMILES string

ClP(Cl)(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H15Cl2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

InChI key

ASWXNYNXAOQCCD-UHFFFAOYSA-N

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Description

  • General description: Dichlorotriphenylphosphorane (Triphenylphosphine dichloride, PPh3Cl2[1]) is a phosphorous halide. Stability and reactivity of dichlorotriphenylphosphorane have been studied by solid state 31P NMR spectroscopy.[2] It participates in the conversion of carboxylic esters to acid halides and mechanism of this cleavage has been investigated.[3] Modified method has been proposed in which dichlorotriphenylphosphorane participates in the synthesis of tertiary amides.[1]
  • Application: Dichlorotriphenylphosphorane may be used in the synthesis of the following:tertiary benzanilide derivatives[4]N-phosphodipeptides[5]dialkyl phosphorochloridites based on the reaction of trialkyl phosphites[6]naphthalene ring-based calix[3]amide, via reaction with 6-amino-2-naphthoic acid[7]C2v-symmetrical cyclic tetramers of aromatic amides[8]

SAFETY INFORMATION

Pictograms

GHS02,GHS08,GHS05

Signal Word

Danger

Hazard Statements

H228,H314,H350

Precautionary Statements

P210 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Carc. 1B - Eye Dam. 1 - Flam. Sol. 2 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup