405957

Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite

98%

Manufacturer: Sigma Aldrich

CAS Number: 66470-81-3

Synonym(S): Tris(2H-perfluoro-2-propyl) phosphite

Select a Size

Pack Size SKU Availability Price
1 G 405957-1-G In Stock ₹ 10,424.48

405957 - 1 G

₹ 10,424.48

In Stock

Quantity

1

Base Price: ₹ 10,424.48

GST (18%): ₹ 1,876.406

Total Price: ₹ 12,300.886

Quality Level

100

Assay

98%

form

liquid

refractive index

n20/D 1.300 (lit.)

bp

130 °C (lit.)

density

1.69 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(OP(OC(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)C(F)(F)F)C(F)(F)F

InChI

1S/C9H3F18O3P/c10-4(11,12)1(5(13,14)15)28-31(29-2(6(16,17)18)7(19,20)21)30-3(8(22,23)24)9(25,26)27/h1-3H

InChI key

MJOVEPJSFHDSOJ-UHFFFAOYSA-N

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Description

  • General description: Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) is a sterically hindered, weakly σ-donating and strongly π-accepting ligand.[1] It can be prepared by the reaction of lithium salt of 1,1,1,3,3,3-hexafluoro-2-propoxide with PCl3.[2] It reacts with nucleosides to form deoxyribonucleoside 3′-bis(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite units.[3]
  • Application: Tris(1,1,1,3,3,3-hexafluoro-2-propyl) phosphite (tris(1,1,1,3,3,3-hexafluoroisopropyl) phosphite) may be used in the following processes:Preparation of new phosphonylating and coupling agents for the synthesis of oligodeoxyribonucleotides.[2]Preparation of nucleoside H-phosphonate units.[4]Synthesis of tetrakis(1,1,1,3,3,3-hexafluoroisopropoxy)(phenylthio)phosphorane by reacting with 1,1,1,3,3,3-hexafluoroisopropyl benzenesulfenate.[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves