423939

Phenyl trifluoromethanesulfonate

98%

Manufacturer: Sigma Aldrich

CAS Number: 17763-67-6

Synonym(S): Phenyl triflate

Select a Size

Pack Size SKU Availability Price
5 ML 423939-5-ML In Stock ₹ 11,900.00

423939 - 5 ML

₹ 11,900.00

In Stock

Quantity

1

Base Price: ₹ 11,900.00

GST (18%): ₹ 2,142.00

Total Price: ₹ 14,042.00

Assay

98%

form

liquid

refractive index

n20/D 1.435 (lit.)

bp

99-100 °C/60 mmHg (lit.)

density

1.396 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)S(=O)(=O)Oc1ccccc1

InChI

1S/C7H5F3O3S/c8-7(9,10)14(11,12)13-6-4-2-1-3-5-6/h1-5H

InChI key

GRJHONXDTNBDTC-UHFFFAOYSA-N

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Description

  • General description: Phenyl trifluoromethanesulfonate (phenyl triflate) is an aryl fluorosulphonate. It has been synthesized by the reaction of phenol with fluorosulphonic anhydride.[1]
  • Application: Phenyl trifluoromethanesulfonate (phenyl triflate) may be used in the following studies:As an arylating agent for the asymmetric α-arylation of ketones catalyzed by Pd(dba)2 and difluorphos.[2]As a reactant in the one pot synthesis of carbazoles by palladium-catalyzed N-arylation of anilines with phenyl triflate followed by oxidative coupling.[3]Synthesis of N-(2,6-diarylbenzoyl)anilines by diarylation of benzanilides with phenyl triflate in the presence of palladium-based catalyst.[4]As an arylating agent in the synthesis of (R)-2-phenyl-2,3-dihydrofuran by the arylation of 2,3-dihydrofuran.[5]

SAFETY INFORMATION

Pictograms

GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301 + H311,H314

Precautionary Statements

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P361 + P364 - P405

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

159.8 °F

Flash Point(C)

71 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves