Description

• Application: 4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions[1][2] and it can be used as a reagent for:Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.[3] Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.[4] Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.[5] Triethylamine-catalyzed three-component Hantzsch condensations.[6] Copper-catalyzed nitrations.[7] Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.[8] Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.[9] Palladium-catalyzed aerobic oxidative cross-coupling reactions.[10] The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.[11]The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.[12]The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.[13]A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.
• Other Notes: Contains varying amounts of anhydride