679011

2-(Diphenylphosphino)terephthalic acid 1-methyl 4-pentafluorophenyl diester

97%

Manufacturer: Sigma Aldrich

CAS Number: 932710-65-1

Synonym(S): 1-Methyl-4-(pentafluorophenyl)-2-(diphenylphosphino)-1,4-benzenedicarboxylate

Select a Size

Pack Size SKU Availability Price
25 MG 679011-25-MG In Stock ₹ 13,065.78
100 MG 679011-100-MG In Stock ₹ 49,675.93

679011 - 25 MG

₹ 13,065.78

In Stock

Quantity

1

Base Price: ₹ 13,065.78

GST (18%): ₹ 2,351.84

Total Price: ₹ 15,417.62

Quality Level

100

Assay

97%

form

solid

reaction suitability

reaction type: click chemistry

mp

109-111 °C

storage temp.

−20°C

SMILES string

COC(=O)c1ccc(cc1P(c2ccccc2)c3ccccc3)C(=O)Oc4c(F)c(F)c(F)c(F)c4F

InChI

1S/C27H16F5O4P/c1-35-27(34)18-13-12-15(26(33)36-25-23(31)21(29)20(28)22(30)24(25)32)14-19(18)37(16-8-4-2-5-9-16)17-10-6-3-7-11-17/h2-14H,1H3

InChI key

OURNVXDJALDDIG-UHFFFAOYSA-N

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Description

  • Application: Staudinger ligation reagent for the conjugation of amine and azide containing compounds or biomolecules.The amine functionalized molecule first reacts with the phosphine through the activated pentafluorophenyl ester.The azide-molecule is then reacted with the newly labeled phosphine to form the iminophosphorane, and the aza-ylide is subsequently captured by the methyl ester to yield the covalent conjugated product.[1]The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable