81831

Propargyl bromide solution

purum, ~80% in toluene

Manufacturer: Sigma Aldrich

CAS Number: 106-96-7

Synonym(S): 3-Bromo-1-propyne

Select a Size

Pack Size SKU Availability Price
50 ML 81831-50-ML In Stock ₹ 4,503.20
250 ML 81831-250-ML In Stock ₹ 16,486.48

81831 - 50 ML

₹ 4,503.20

In Stock

Quantity

1

Base Price: ₹ 4,503.20

GST (18%): ₹ 810.576

Total Price: ₹ 5,313.776

grade

purum

Quality Level

200

form

liquid

contains

~0.3% magnesium oxide light as stabilizer

concentration

~80% in toluene

density

1.39 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

BrCC#C

InChI

1S/C3H3Br/c1-2-3-4/h1H,3H2

InChI key

YORCIIVHUBAYBQ-UHFFFAOYSA-N

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Description

  • General description: The product is 80% solution of propargyl bromide in toluene. Propargyl bromide (3-bromopropyne, C3H3Br, or 3BP)[1] possess propargyl group, which is an important three-carbon building block. It participates in the stereoselective propargylation reaction of α-alkoxy aldehydes.[1] It is used to compose a soil fumigant trizone.[2]
  • Application: Propargyl bromide solution may be used in the synthesis of the following:new arabinogalactan propargyl ethers with degree of substitution (DS) up to 2.8, by propargylation of arabino-3,6-galactan[3]conjugated polyelectrolyte with polyacetylene as the backbone and pyridinium as side groups, poly(propargyl pyridinium bromide)[4]benzodiazepine derivative, 4-phenyl-1-(prop-2-yn-1-yl)-1H-1,5-benzodiazepin-2(3H)-one[5]N(3)-propargylated 2′-deoxyuridine, which can be encorporated in the DNA[6]chiral oxygenated acyclic natural products, via distereoselective propargylation of α-hydroxy aldehydes[1]

SAFETY INFORMATION

Pictograms

GHS02,GHS06,GHS08,GHS05

Signal Word

Danger

Hazard Statements

H225,H301,H304,H314,H335,H336,H361d,H373

Precautionary Statements

P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

WGK

WGK 3

Flash Point(F)

64.4 °F

Flash Point(C)

18 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves