275891

Dichloro(1,5-cyclooctadiene)palladium(II)

99%

Manufacturer: Sigma Aldrich

CAS Number: 12107-56-1

Synonym(S): PdCl2(cod)

Select a Size

Pack Size SKU Availability Price
2 G 275891-2-G In Stock ₹ 20,967.90

275891 - 2 G

₹ 20,967.90

In Stock

Quantity

1

Base Price: ₹ 20,967.90

GST (18%): ₹ 3,774.222

Total Price: ₹ 24,742.122

Quality Level

100

Assay

99%

reaction suitability

core: palladiumreaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Cross Couplingsreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Pd]Cl.C1CC=CCCC=C1

InChI

1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

InChI key

RRHPTXZOMDSKRS-PHFPKPIQSA-L

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Description

  • Application: Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation.[1][2] It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes[3]; the synthesis of benzo[b]thiophenes from thioenols[4] and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves