345350

(1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Manufacturer: Sigma Aldrich

CAS Number: 104322-63-6

Synonym(S): (1S)-(+)-(Camphorylsulfonyl)oxaziridine, (1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam

Select a Size

Pack Size SKU Availability Price
1 G 345350-1-G In Stock ₹ 6,679.03

345350 - 1 G

₹ 6,679.03

In Stock

Quantity

1

Base Price: ₹ 6,679.03

GST (18%): ₹ 1,202.225

Total Price: ₹ 7,881.255

form

solid

Quality Level

200

optical activity

[α]28/D +45°, c = 2 in chloroform

impurities

<1% toluene

mp

172-174 °C (lit.)

storage temp.

2-8°C

SMILES string

CC1(C)[C@@H]2CC[C@]13CS(=O)(=O)N4O[C@@]34C2

InChI

1S/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9+,10+,11?/m1/s1

InChI key

GBBJBUGPGFNISJ-YDQXZVTASA-N

Other Options

Image Product Name Manufacturer Price Range
104322-63-6 | (1S)-(+)-(10-Camphorsulfonyl)oxaziridine
-- ₹ 445.00 - ₹ 9,701.00

Related Products

Img

Sigma Aldrich

349003

--

Img

Sigma Aldrich

318361

99%...

Img

Sigma Aldrich

35603

≥97.0% (T)...

Img

Sigma Aldrich

309664

99%...

Img

Sigma Aldrich

C2107

99%...

Img

Sigma Aldrich

35605

≥95.0% (T)...

Img

Sigma Aldrich

359939

97%...

Img

Sigma Aldrich

470600

97%...

Description

  • Application: (1S)-(+)-(10-Camphorsulfonyl)oxaziridine can be used:To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation.[1]In the synthesis of thymidine oligonucleotides connected through pyrophosphates.[2]In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide.[3]In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate.[4]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves