404438

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

98%

Manufacturer: Sigma Aldrich

CAS Number: 135616-36-3

Synonym(S): (S,S)-Jacobsen’s ligand

Select a Size

Pack Size SKU Availability Price
5 G 404438-5-G In Stock ₹ 23,197.98

404438 - 5 G

₹ 23,197.98

In Stock

Quantity

1

Base Price: ₹ 23,197.98

GST (18%): ₹ 4,175.636

Total Price: ₹ 27,373.616

Quality Level

100

Assay

98%

optical activity

[α]20/D +315 to 15°, c = 1 in methylene chloride

mp

203-206 °C (lit.)

SMILES string

CC(C)(C)c1cc(\C=N\[C@H]2CCCC[C@@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C

InChI

1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m0/s1

InChI key

FYNXDGNCEBQLGC-GTHUDTLPSA-N

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Description

  • Application: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.[1][2][3]
  • Legal Information: Licensed through Research Corporation Technologies

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves