638021

DavePhos

97%

Manufacturer: Sigma Aldrich

CAS Number: 213697-53-1

Synonym(S): 2-Dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl

Select a Size

Pack Size SKU Availability Price
1 G 638021-1-G In Stock ₹ 17,103.50
5 G 638021-5-G In Stock ₹ 43,657.23
25 G 638021-25-G In Stock ₹ 1,63,879.68
100 G 638021-100-G In Stock ₹ 4,32,664.43

638021 - 1 G

₹ 17,103.50

In Stock

Quantity

1

Base Price: ₹ 17,103.50

GST (18%): ₹ 3,078.63

Total Price: ₹ 20,182.13

Quality Level

200

Assay

97%

reaction suitability

reaction type: Cross Couplingsreagent type: ligandreaction type: Arylationsreagent type: ligandreaction type: Buchwald-Hartwig Cross Coupling Reactionreagent type: ligandreaction type: Hydroaminationsreagent type: ligandreaction type: Kumada Couplingreagent type: ligandreaction type: Negishi Couplingreagent type: ligandreaction type: Suzuki-Miyaura Coupling

mp

121-124 °C (lit.)

functional group

phosphine

SMILES string

CN(C)c1ccccc1-c2ccccc2P(C3CCCCC3)C4CCCCC4

InChI

1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3

InChI key

ZEMZPXWZVTUONV-UHFFFAOYSA-N

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Description

  • Application: DavePhos may be used as a ligand in the following reactions:Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylides with different aryl chlorides to yield functionalized pyridines.[1]Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides.[2]C-C Coupling of 3-haloquinolines with aryl sulfinates via palladium-catalyzed desulfitative arylation to form the corresponding biaryl compounds.[3]
  • Legal Information: Usage subject to US Patents 6307087 and 6395916.

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves