656631

1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride

95%

Manufacturer: Sigma Aldrich

CAS Number: 173035-10-4

Synonym(S): 1,3-Dimesitylimidazolidinium chloride, 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride, 4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride, N,N′-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride

Select a Size

Pack Size SKU Availability Price
1 G 656631-1-G In Stock ₹ 10,143.03
5 G 656631-5-G In Stock ₹ 20,838.13

656631 - 1 G

₹ 10,143.03

In Stock

Quantity

1

Base Price: ₹ 10,143.03

GST (18%): ₹ 1,825.745

Total Price: ₹ 11,968.775

Quality Level

100

Assay

95%

reaction suitability

reagent type: ligand

mp

280-286 °C

SMILES string

[Cl-].Cc1cc(C)c(N2CC[N+](=C2)c3c(C)cc(C)cc3C)c(C)c1

InChI

1S/C21H27N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h9-13H,7-8H2,1-6H3;1H/q+1;/p-1

InChI key

COGMCBFILULEOS-UHFFFAOYSA-M

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Description

  • General description: 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride is an NHC (N-heterocyclic carbene) ligand which can bind with metal pre-catalysts to form complexes that show high catalytic activity.
  • Application: N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts used for: A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.[1]Markovnikov-type hydration of terminal alkynes[2]Hydrosilylation of ketones and cycloaddition of azides and alkynes[3]Suzuki-Miyaura reactions[4]Luminescence experiments[5]

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves