674737

(R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol

96%

Manufacturer: Sigma Aldrich

CAS Number: 111822-69-6

Synonym(S): (R)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthalene-2,2′-diol

Select a Size

Pack Size SKU Availability Price
100 MG 674737-100-MG In Stock ₹ 16,421.53

674737 - 100 MG

₹ 16,421.53

In Stock

Quantity

1

Base Price: ₹ 16,421.53

GST (18%): ₹ 2,955.875

Total Price: ₹ 19,377.405

Quality Level

100

Assay

96%

form

solid

optical activity

[α]20/D +114°, c = 1 in chloroform

mp

103-145 °C

SMILES string

Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)[Si](c5ccccc5)(c6ccccc6)c7ccccc7)[Si](c8ccccc8)(c9ccccc9)c%10ccccc%10

InChI

1S/C56H42O2Si2/c57-55-51(59(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)58)60(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40,57-58H

InChI key

STBZSRVMGWTCOU-UHFFFAOYSA-N

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Description

  • Application: (R)-3,3′-Bis(triphenylsilyl)-1,1′-bi-2-naphthol reacts with trimethylaluminum to form a chiral organoaluminum reagent, which can catalyze the asymmetric Diels-Alder reaction of cyclopentadiene and methyl acrylate to form the corresponding Diels-Alder adduct.[1]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable