682144
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
96%
Manufacturer: Sigma Aldrich
CAS Number: 364732-88-7
Synonym(S): (R)-Phanephos
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 682144-100-MG | In Stock | ₹ 11,712.65 |
| 500 MG | 682144-500-MG | In Stock | ₹ 48,593.43 |
682144 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 11,712.65
GST (18%): ₹ 2,108.277
Total Price: ₹ 13,820.927
Quality Level
100
Assay
96%
form
solid
optical activity
[α]/D -34±4°, c = 1 in chloroform
mp
222-226 °C
InChI
1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2
InChI key
GYZZZILPVUYAFJ-UHFFFAOYSA-N
Other Options
Related Products
Description
- Application: (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane may be used as a ligand in the following processes:Enantioselective reductive cyclization of 1,6-enynes via asymmetric hydrogenation in the presence of a rhodium catalyst to form alkylidene-substituted heterocycles.[1]Asymmetric hydroboration of 3,3-disubstituted cyclopropenes to form 2,2-disubstituted cyclopropyl boronates.[2]Asymmetric ring-opening reactions of azabenzonorbornadienes in the presence of zinc(II) triflate and palladium(II) acetate to form aminodihydronaphthalenes.[3]
- Legal Information: Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US5874629 and any patents arising therefrom apply.
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves