698253

Tris(3,5-dimethylphenyl)phosphine

96%

Manufacturer: Sigma Aldrich

CAS Number: 69227-47-0

Synonym(S): Tri-3,5-xylylphosphine

Select a Size

Pack Size SKU Availability Price
1 G 698253-1-G In Stock ₹ 8,129.58

698253 - 1 G

₹ 8,129.58

In Stock

Quantity

1

Base Price: ₹ 8,129.58

GST (18%): ₹ 1,463.324

Total Price: ₹ 9,592.904

Quality Level

100

Assay

96%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: ligand

mp

160-165 °C

functional group

phosphine

SMILES string

Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3

InChI

1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3

InChI key

XRALRSQLQXKXKP-UHFFFAOYSA-N

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Description

  • Application: Catalyst for:Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enonesHighly selective rhodium-catalyzed hydrogenation reactionsClassical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenesUsed for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanesUsed for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis

SAFETY INFORMATION

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves