700665
(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
Manufacturer: Sigma Aldrich
CAS Number: 864943-22-6
Synonym(S): (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 MG | 700665-100-MG | In Stock | ₹ 25,038.23 |
700665 - 100 MG
In Stock
Quantity
1
Base Price: ₹ 25,038.23
GST (18%): ₹ 4,506.881
Total Price: ₹ 29,545.111
form
solid
Quality Level
100
optical activity
[α]22/D −44.0°, c = 1 in DMSO
mp
390-400 °C
storage temp.
−20°C
SMILES string
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
InChI
1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key
BVICVEIKBNVROI-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
Sigma Aldrich Fine Chemicals Biosciences (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide | 864943-22-6 | MFCD12546016 | 100MG | -- | ₹ 29,654.80 | ||
864943-22-6 | (11Br)-2,6-di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide | -- | ₹ 5,340.00 - ₹ 2,10,574.00 |
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Description
- Application: Catalyst for:Asymmetric hydrogenation cascadeEnantioselective Friedel-Crafts reactionAsymmetric hydrogenation of 2-substituted quinolinesChiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamatesPreparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/estersAsymmetric transfer hydrogenation of substituted quinoxalines
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves