73469

(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene

≥97%

Manufacturer: Sigma Aldrich

CAS Number: 494227-37-1

Synonym(S): (1R,1′R)- 1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M004-1

Select a Size

Pack Size SKU Availability Price
100 MG 73469-100-MG In Stock ₹ 10,251.28
1 G 73469-1-G In Stock ₹ 61,074.65
50 G 73469-50-G In Stock ₹ 8,43,635.55
100 G 73469-100-G In Stock ₹ 14,17,284.78

73469 - 100 MG

₹ 10,251.28

In Stock

Quantity

1

Base Price: ₹ 10,251.28

GST (18%): ₹ 1,845.23

Total Price: ₹ 12,096.51

Quality Level

100

Assay

≥97%

form

powder

optical purity

ee: ≥99%

SMILES string

[Fe].COc1c(C)cc(cc1C)P([C]2[CH][CH][CH][C]2[C@H](N(C)C)c3ccccc3)c4cc(C)c(OC)c(C)c4.COc5c(C)cc(cc5C)P([C]6[CH][CH][CH][C]6[C@H](N(C)C)c7ccccc7)c8cc(C)c(OC)c(C)c8

InChI

1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/t2*30-;/m11./s1

InChI key

HEJIDMKBSDYNOY-LJXMUBMNSA-N

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Description

  • General description: Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.[1]
  • Application: It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.[2]
  • Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
  • Other Notes: sold in collaboration with Solvias AG

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves