747769

[Ir(dtbbpy)(ppy)2]PF6

Manufacturer: Sigma Aldrich

CAS Number: 676525-77-2

Synonym(S): [Ir(dtbbpy)(ppy)2][PF6], Ir Photocatalyst, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate

Select a Size

Pack Size SKU Availability Price
50 MG 747769-50-MG In Stock ₹ 9,623.70
100 MG 747769-100-MG In Stock ₹ 17,200.00

747769 - 50 MG

₹ 9,623.70

In Stock

Quantity

1

Base Price: ₹ 9,623.70

GST (18%): ₹ 1,732.266

Total Price: ₹ 11,355.966

form

powder

Quality Level

100

reaction suitability

core: iridiumreaction type: Photocatalysisreagent type: catalyst

photocatalyst activation

455 nm

storage temp.

2-8°C

SMILES string

CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F

InChI

1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;

InChI key

DZARMRZNOUWGQE-UHFFFAOYSA-N

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Description

  • Application: [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.[1]Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.[2]Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.[3]Aryl-alkyl C−C reductive cross-coupling reactions.[4]Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable