tBuXPhos
95%
Manufacturer: Sigma Aldrich
CAS Number: 564483-19-8
Synonym(S): 2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl, t-Bu XPhos, tert-Butyl XPhos
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 G | 901904-1-G | In Stock | ₹ 6,018.70 |
| 5 G | 901904-5-G | In Stock | ₹ 22,602.60 |
| 25 G | 901904-25-G | In Stock | ₹ 39,825.18 |
901904 - 1 G
In Stock
Quantity
1
Base Price: ₹ 6,018.70
GST (18%): ₹ 1,083.366
Total Price: ₹ 7,102.066
Assay
95%
form
powder or crystals
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reactionreaction type: Heck Reactionreaction type: Hiyama Couplingreaction type: Negishi Couplingreaction type: Sonogashira Couplingreaction type: Stille Couplingreaction type: Suzuki-Miyaura Couplingreagent type: catalystreaction type: Cross Couplingsreagent type: ligand
mp
148-151 °C (lit.)150 °C
functional group
phosphine
SMILES string
CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI
1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChI key
SACNIGZYDTUHKB-UHFFFAOYSA-N
Other Options
| Image | Product Name | Manufacturer | Price Range | |
|---|---|---|---|---|
tBuXPhos | -- | ₹ 54.20 - ₹ 5,56,500.00 | ||
564483-19-8 | 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl | -- | ₹ 445.00 - ₹ 3,560.00 |
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Description
- General description: tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.
- Application: tBuXPhos has been used in the preparation of [tBuXPhosAu(MeCN)]BAr4F, a gold catalyst for the intermolecular [2+2] cycloaddition of terminal arylalkynes with substituted alkenes to form functionalized cyclobutenes with high regioselectivity.
- Legal Information: Usage subject to Patents: EP 1097158; JP 5758844; CA 2336691
SAFETY INFORMATION
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable