911828

PhPAd-DalPhos Ni(o-tolyl)Cl

≥95%

Manufacturer: Sigma Aldrich

CAS Number: 2290490-29-6

Synonym(S): (SP-4-3)-Chloro[8-[2-(diphenylphosphino-κP)phenyl]-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane-κP8](2-methylphenyl)nickel

Select a Size

Pack Size SKU Availability Price
250 MG 911828-250-MG In Stock ₹ 59,093.68

911828 - 250 MG

₹ 59,093.68

In Stock

Quantity

1

Base Price: ₹ 59,093.68

GST (18%): ₹ 10,636.862

Total Price: ₹ 69,730.542

Assay

≥95%

form

powder

reaction suitability

reagent type: catalystreaction type: Cross Couplings

mp

235-248 °C

SMILES string

Cl[Ni]1(P(C(C2)(O3)C)(C4=CC=CC=C4P(C5=CC=CC=C5)1C6=CC=CC=C6)[C@@](C[C@]3(OC27C)C)(O7)C)C(C=CC=C8)=C8C

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Description

  • Application: PhPAd-DalPhos Ni(o-tolyl)Cl is an air stable precatalyst developed in the Stradiotto lab used for coupling of bulky primary amines with arenes.
  • Other Notes: Technology Spotlight: DalPhos ligandsPhPAd-DalPhos: Ligand-Enabled, Nickel-Catalyzed Cross-Coupling of (Hetero)aryl Electrophiles with Bulky Primary Alkylamines

SAFETY INFORMATION

Pictograms

GHS08,GHS07,GHS09

Signal Word

Danger

Hazard Statements

H302 + H332,H334,H341,H351,H361f,H372,H410

Precautionary Statements

P202 - P260 - P264 - P273 - P301 + P312 - P308 + P313

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable