673293

Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

Manufacturer: Sigma Aldrich

CAS Number: 92361-49-4

Synonym(S): Cp*RuCl(PPh3)2, Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

Select a Size

Pack Size SKU Availability Price
250 MG 673293-250-MG In Stock ₹ 15,462.30
1 G 673293-1-G In Stock ₹ 44,277.90

673293 - 250 MG

₹ 15,462.30

In Stock

Quantity

1

Base Price: ₹ 15,462.30

GST (18%): ₹ 2,783.214

Total Price: ₹ 18,245.514

form

solid

Quality Level

100

reaction suitability

core: rutheniumreagent type: catalystreaction type: click chemistry

mp

128 °C (D)

storage temp.

2-8°C

SMILES string

Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1

InChI key

KLXKSZDVKAWYRT-UHFFFAOYSA-M

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Description

  • Application: Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".[1]

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable