392731

(DHQD)2PHAL

≥95%

Manufacturer: Sigma Aldrich

CAS Number: 140853-10-7

Synonym(S): Hydroquinidine 1,4-phthalazinediyl diether

Select a Size

Pack Size SKU Availability Price
1 G 392731-1-G In Stock ₹ 16,300.00

392731 - 1 G

₹ 16,300.00

In Stock

Quantity

1

Base Price: ₹ 16,300.00

GST (18%): ₹ 2,934.00

Total Price: ₹ 19,234.00

Assay

≥95%

form

powder

optical activity

[α]22/D −262°, c = 1.2 in methanol

greener alternative product score

old score: 5new score: 3Find out more about DOZN™ Scoring

greener alternative product characteristics

Waste PreventionLess Hazardous Chemical SynthesesSafer Solvents and AuxiliariesInherently Safer Chemistry for Accident PreventionLearn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

160 °C (dec.) (lit.)

greener alternative category

, Re-engineered

SMILES string

CC[C@H]1CN2CCC1CC2[C@@H](Oc3nnc(O[C@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c8ccccc38)c9ccnc%10ccc(OC)cc9%10

InChI

1S/C48H54N6O4/c1-5-29-27-53-21-17-31(29)23-43(53)45(35-15-19-49-41-13-11-33(55-3)25-39(35)41)57-47-37-9-7-8-10-38(37)48(52-51-47)58-46(44-24-32-18-22-54(44)28-30(32)6-2)36-16-20-50-42-14-12-34(56-4)26-40(36)42/h7-16,19-20,25-26,29-32,43-46H,5-6,17-18,21-24,27-28H2,1-4H3/t29-,30-,31-,32-,43+,44+,45-,46-/m0/s1

Other Options

Image Product Name Manufacturer Price Range
Sigma Aldrich Fine Chemicals Biosciences (DHQD)2PHAL | 140853-10-7 | MFCD00198107 | 1g
-- ₹ 19,406.45
(DHQD)2PHAL
-- ₹ 1,335.00 - ₹ 19,847.00

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Description

  • General description: (DHQD)2PHAL is a dimer that can be used as a chiral amine catalyst for asymmetric halogenations.[1][2](DHQD)2PHAL is a modified cinchona alkaloid derivative mainly used as a ligand for enantioselective catalysis.[3]
  • Application: (DHQD)2PHAL may be used as ligand for:Osmium trioxide catalyzed asymmetric dihydroxylation of olefins.[3]Palladium catalyzed Suzuki-Miyaura coupling of aryl/heteroaryl halides with aryl boronic acids in aqueous medium and in the absence of phosphine/organic solvent.[4]Copper(I)-catalyzed azide-alkyne cycloaddition reaction to synthesize 1,2,3-triazoles in water.[5]
  • Legal Information: Sold under license from Rhodia Pharma Solutions.

SAFETY INFORMATION

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves